MABS Institution
11th Chemistry Monthly Test - 1 ( Fundamentals of Organic Chemistry )-Aug 2020
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Why is a solution of potassium hydroxide used to absorb carbon dioxide evolved during the estimation of carbon present in an organic compound?
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Write the common name for the following compounds.
(i) CH3 OH
(ii) C2H5OH
(iii) C2H5-O-C2-H5
(iv) CH3 COOH -
What is tautomerism?
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How many sigma and pi bonds are present in
(i) \({ CH }_{ 3 }-C\equiv N\)
(ii) \({ CH }_{ 3 }=C=N?\) -
What are enantiomers?
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Suggest and explain the method suitable to purify the organic compounds depending on their boiling points.
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In an estimation of sulphur by Carius method, 0.468 of an organic sulphur compound gave 0.668 g of barium sulphate. Find the percentage of sulphur in the compound.
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Draw the structures of
(I) 3-methylpentanal
(ii) 5-hydroxy 2,2-dimethyl heptanoic acid
(iii) 2-ethyl-4-propylpentane-dioic acid -
How would you detect the halogens in an organic compound?
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Write the possible isomers for the formula C5H12 with their names and structures.
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Complete the following reactions:
(i) \(({ CH }_{ 3 }COO)_{ 2 }pb+Na_{ 2 }S\rightarrow ?\)
(ii) \({ Na }_{ 2 }[(Fe(CN)_{ 5 }NO]+{ Na }_{ 2 }S\rightarrow ?\)
(iii) \(NaCNS+FeCI_{ 3 }\rightarrow ?\)
(iv) \(Na_{ 2 }S+AgNO_{ 3 }\rightarrow ?\)
(v) \(BaCI_{ 2 }+{ Na }_{ 2 }{ SO }_{ 4 }\rightarrow ?\)
(vi) \({ Na }_{ 4 }[Fe(CN)_{ 6 }]+{ FeCI }_{ 3 }\rightarrow ?\) -
0.24 g of organic compound containing phosphorous gave 0.66 g of Mg2P2O7 by the usual analysis. Calculate the percentage of phosphorous in the compound.
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Arrange the following in increasing order of C-C bond length: C2 H6, C2 H4, C2 H2.
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Write structural formula for the following compounds
(i) Cyclohexa-1, 4-diene
(ii) Ethynyl cyclohexane. -
0.26g of an organic compound gave 0.039 g of water and 0.245 g of carbon dioxide on combustion. Calculate the percentage of C & H.
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An organic compound contains 69% carbon and 4.9% hydrogen, the remainder being oxygen. Calculate the masses of carbon dioxide and water produced when 0.20 g of this compound is subjected to complete combustion.
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How will you estimate phosphorous in an organic compound?
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Describe tautomerism with relevant examples.
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How will you detect the presence of carbon and hydrogen in an organic compound? Copper oxide test:
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Explain about the steps involved in naming an organic compound as per IUPAC nomenclature.
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Consider the structures I to VII and answer the following questions (i) to (v)
(i) CH3-CH2-CH2-CH2-OH
(ii) \({ CH }_{ 3 }-{ CH }_{ 2 }-\underset { \overset { | }{ OH } }{ CH } -{ CH }_{ 3 }\)
(iii) \({ CH }_{ 3 }-\overset { \underset { | }{ { CH }_{ 3 } } }{ \underset { \overset { | }{ { CH }_{ 3 } } }{ C } } -{ CH }_{ 3 }\)
(iv) \({ CH }_{ 3 }-\underset { \overset { | }{ { CH }_{ 3 } } }{ { CH }_{ 3 } } -{ CH }_{ 2 }-OH\)
(v) CH3 -CH2 -O-CH2 -CH3
(vi) CH3 - O - CH2 - CH2 - CH3
(vii) \({ CH }_{ 3 }-O-\underset { \overset { | }{ { CH }_{ 3 } } }{ { CH } } -{ CH }_{ 3 }\)
(i) Which of the above compounds form pairs of metamers?
(ii) Identify the pairs of compounds which are functional isomers.
(iii) Identify the pairs of compounds that represent position isomerism.
(iv) Identify the pairs of compounds that represent chain isomerism.
(v) Does any of these compounds possess geometrical isomerism? If yes identify them. If no, give reason.
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Explain about thin layer chromatography.
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Explain the following with example.
(i) Fisher projection formula
(ii) Saw horse projection formula
(iii) Newman projection formula
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Explain about the estimation of halogens by carius method.